NITROSONIUM NITRATE, AN ISOMER OF N2O4 IN IF5

Citation
Xz. Zhang et K. Seppelt, NITROSONIUM NITRATE, AN ISOMER OF N2O4 IN IF5, Zeitschrift fur anorganische und allgemeine Chemie, 624(4), 1998, pp. 667-670
Citations number
31
Language
TEDESCO
art.tipo
Article
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
0044-2313 → ACNP
Volume
624
Issue
4
Year of publication
1998
Pages
667 - 670
Database
ISI
SICI code
0044-2313(1998)624:4<667:NNAION>2.0.ZU;2-G
Abstract
N2O4 dissolves in IF5 as NO+NO3-, as established by n.m.r spectroscopy , and in the solid state the solvate complex NO+NO3-. IFS is formed. T his contains a double chain of alternating NO+ cations and NO3- anions . (a = 483.4(2), b = 773.9(1), c = 932.6(3) pm, (alpha = 70.18(2)degre es, beta = 80.90(3)degrees, (gamma = 87.34(2)degrees, space group P (1 ) over bar, Z = 2).