ICHLOROBIS(N,N-DIETHYLDITHIOCARBAMATO-S,S')TIN(IV)

Citation
R. Bohra et al., ICHLOROBIS(N,N-DIETHYLDITHIOCARBAMATO-S,S')TIN(IV), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1447-1449
Citations number
9
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Crystallography
ISSN journal
0108-2701
Volume
50
Year of publication
1994
Part
9
Pages
1447 - 1449
Database
ISI
SICI code
0108-2701(1994)50:<1447:I>2.0.ZU;2-#
Abstract
The structural features of the title complex, [SnCl2(C5H10NS2)2], are significantly different to those of the complexes Me2Sn(S2CNR2)2 that have been structurally characterized so far. In the title complex the geometry around the Sn atom is cis-octahedral with a Cl-Sn-Cl angle of 91.85 (3)-degrees and an average Sn-Cl bond length of 2.404 (7) angst rom. Both dithiocarbamato groups behave as bidentate chelating ligands with an average Sn-S bond length of 2.539 (6) angstrom and an average S-Sn-S bond angle of 71.01 (2)-degrees.