ISOLATION AND CHARACTERIZATION OF THE ETHYLENE-BRIDGED ZIRCONOCENE COMPLEX (CP(2)ZRME)(2)(CH2CH2)

Citation
T. Takahashi et al., ISOLATION AND CHARACTERIZATION OF THE ETHYLENE-BRIDGED ZIRCONOCENE COMPLEX (CP(2)ZRME)(2)(CH2CH2), Organometallics, 13(9), 1994, pp. 3413-3414
Citations number
45
Language
INGLESE
art.tipo
Note
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
0276-7333
Volume
13
Issue
9
Year of publication
1994
Pages
3413 - 3414
Database
ISI
SICI code
0276-7333(1994)13:9<3413:IACOTE>2.0.ZU;2-0
Abstract
An ethylene-bridged zirconocene complex, (Cp(2)ZrMe)2(CH2CH2), was pre pared by the reaction of Cp(2)ZrMe(2) with a zirconocene-ethylene comp lex, [Cp(2)ZrEt(CH2=CH2)]MgBr, and the structure of this complex was d etermined by a single-crystal X-ray diffraction study. The structure o f this complex showed one methyl group on each zirconium and an ethyle ne ligand simultaneously coordinating to the two zirconocene moieties.