CHANGES IN MOLECULAR KLL AUGER SPECTRUM OF FLUORINE ON GOING FROM HF TO LIF, NAF, AND KF

Citation
Op. Sairanen et al., CHANGES IN MOLECULAR KLL AUGER SPECTRUM OF FLUORINE ON GOING FROM HF TO LIF, NAF, AND KF, Chemical physics letters, 215(4), 1993, pp. 353-356
Citations number
16
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
0009-2614
Volume
215
Issue
4
Year of publication
1993
Pages
353 - 356
Database
ISI
SICI code
0009-2614(1993)215:4<353:CIMKAS>2.0.ZU;2-2
Abstract
The molecular KLL Auger spectra of fluorine have been measured from HF , LiF, NaF, and KF. The change in the ionic character of the chemical bond is clearly seen as narrowing of the KL(2,3)L(2,3) structure on go ing from HF to KF. Theoretical calculations using the multiconfigurati onal CASSCF method are also found to predict well these changes. Compa rison with the calculated KLL Auger spectrum of the fluorine ion F- ve rifies the conclusions.