ENANTIOSELECTIVE ALLYLATION AND T-BUTYLATION OF 2-CYCLOHEXENONE IN AQUEOUS-MEDIA IN THE PRESENCE OF BETA-CYCLODEXTRINS AS CHIRAL AUXILIARIES

Citation
R. Fornasier et al., ENANTIOSELECTIVE ALLYLATION AND T-BUTYLATION OF 2-CYCLOHEXENONE IN AQUEOUS-MEDIA IN THE PRESENCE OF BETA-CYCLODEXTRINS AS CHIRAL AUXILIARIES, Gazzetta chimica italiana, 126(9), 1996, pp. 633-634
Citations number
6
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
ISSN journal
0016-5603
Volume
126
Issue
9
Year of publication
1996
Pages
633 - 634
Database
ISI
SICI code
0016-5603(1996)126:9<633:EAATO2>2.0.ZU;2-T
Abstract
beta-Cyclodextrins promote enantioselective allylation and t-butylatio n of 2-cyclohexenone, using Zn dust and alkyl halides in 5:1 (v/v) H2O -THF, affording optically active products with e.e. up to 50%.