THE 2-NU(2) BAND OF HOCL

Citation
F. Cavazza et al., THE 2-NU(2) BAND OF HOCL, Gazzetta chimica italiana, 126(8), 1996, pp. 539-541
Citations number
13
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
ISSN journal
0016-5603
Volume
126
Issue
8
Year of publication
1996
Pages
539 - 541
Database
ISI
SICI code
0016-5603(1996)126:8<539:T2BOH>2.0.ZU;2-5
Abstract
The first overtone of the bending mode of HOCl has been observed in th e region between 2300 and 2800 cm(-1) at a resolution of 0.010 cm. Abo ut 2000 vibration-rotation transitions for (HOCl)-Cl-35 and 800 for (H oCl)-Cl-37 have been assigned and analyzed by adopting a Watson-type H amiltonian in the S reduction and I-r representation. Improved sets of molecular constants derived for the v(2)=2 state of both isotopic spe cies reproduce the observed transitions within their experimental accu racy.