A NEW MECHANISTIC MODEL FOR HYDRIDE TRANSFER RELATED TO THE REDOX COUPLE NADH NAD(+) - CRITICISM ON THE QUANTUM-CHEMICAL MO APPROACH/

Authors
Citation
Hm. Buck, A NEW MECHANISTIC MODEL FOR HYDRIDE TRANSFER RELATED TO THE REDOX COUPLE NADH NAD(+) - CRITICISM ON THE QUANTUM-CHEMICAL MO APPROACH/, Recueil des travaux chimiques des Pays-Bas, 115(6), 1996, pp. 329
Citations number
30
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
ISSN journal
0165-0513
Volume
115
Issue
6
Year of publication
1996
Database
ISI
SICI code
0165-0513(1996)115:6<329:ANMMFH>2.0.ZU;2-3
Abstract
A mechanistic study of hydride transfer based on (simplified) NADH/NAD (+) model systems is given. The new model originates from a classical mechanism generally indicated as being an intramolecular nucleophilic displacement reaction. There is some controversy with the results of q uantum-chemical calculations.