CIS-DI(NITRATO-O,O')BIS(TRICYCLOHEXYLPHOSPHINE OXIDE-O)NICKEL(II)

Citation
Ar. Kennedy et al., CIS-DI(NITRATO-O,O')BIS(TRICYCLOHEXYLPHOSPHINE OXIDE-O)NICKEL(II), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 292-293
Citations number
15
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Crystallography
ISSN journal
0108-2701
Volume
53
Year of publication
1997
Part
3
Pages
292 - 293
Database
ISI
SICI code
0108-2701(1997)53:<292:CO>2.0.ZU;2-3
Abstract
The formal pseudo-octahedral coordination around the Ni-II atom in the title complex, [Ni(NO3)(2)(OPCy(3))(2)], places the OPCy(3) ligands ( C18H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conforma tion. This may be rationalized try viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.