K. Saito et al., DEVELOPMENT OF NEW LIGNIN DERIVATIVES AS SOIL CONDITIONING AGENTS BY RADICAL SULFONATION AND ALKALINE-OXYGEN TREATMENT, Mokuzai Gakkaishi, 43(8), 1997, pp. 669-677
It is well known that aluminium ions eluted into soil solutions under
acidic conditions are toxic for plants. Such soil containing excess al
uminium ions are distributed in the tropics of South-East Asia, and pr
event cultivation and reforestation. To develop anew soil conditioning
agent from lignin, kraft lignin was modified by radical sulfonation a
nd alkaline-oxygen treatment, and its ability as a soil conditioning a
gent was examined. Lignins modified by radical sulfonation showed sequ
estering abilities for aluminium ions in the range of pH 4.0-5.6, and
the growth rate of radish roots measured by neutron radiography and th
e line intersection method indicated that the modified lignin was able
to remove the toxic effect of aluminium ions and even to improve the
growth rate of the radish roots.